Krampf #149 A Ball of Oil


Krampf@aol.com


For this week's experiment, we are going to make a ball of oil. Don't
worry, this is not nearly as messy as it sounds. You will need:

* a clear container. I used a tall, thin bud vase, but you can
use a drinking glass, etc.
* water
* rubbing alcohol
* cooking oil
* a drinking straw

Fill the container 1/2 full of water. Tilt the glass and SLOWLY and
CAREFULLY pour alcohol along the side of the glass to fill it near
the top. Place the glass on a flat surface. Looking from the side, it
will seem that the water and alcohol have mixed, but unless you were
in too much of a hurry, they have not.

Dip the end of the drinking straw into the cooking oil. Place your
finger over the top end of the straw and lift it out of the oil. One
or more drops of oil will stay in the end of the straw. Hold the
straw over the glass of water and alcohol, near the surface. Remove
your finger and the oil will drop into the glass. Each drop of oil
will sink about halfway through the liquid and then stop, forming a
round ball of oil that floats there. If you make several drops, they
will each form a ball and the balls usually do not join unless forced
together or touched by something like the end of the straw.

What is going on? Several different scientific principles are at work
here. First, the alcohol is less dense than the water. One cubic inch
of alcohol weighs less than one cubic inch of water. This lets the
alcohol float on top of the water, forming two layers of liquid.

The oil is denser than the alcohol, so it sinks through that layer.
The oil is less dense than the water, so it floats on that layer.
This causes the oil to float in the middle of the glass.

OK, so now we know why the oil is in the middle. Now, why does it
make a ball? The oil will not mix with the water or the alcohol.
Water and alcohol are both polar liquids. That means that one end of
the molecule has a slight positive charge and the other end has a
slight negative charge. Oil is a non-polar liquid, and it does not
have these charges on the ends. Polar liquids will mix with polar
liquids. If you stir the liquid in your glass, the water and alcohol
will mix. Non-polar liquids mix with non-polar liquids. If you stir
two different kinds of oil together, they will mix. Polar and non-
polar liquids will not mix, so the oil remains separate from the
water and alcohol.

The oil forms a ball because of pressure. The liquid around it is
pushing inwards equally in every direction. The oil is pushing
outwards equally in every direction. This equal pressure causes the
oil to form a ball. If your oil ball is large enough, You may see it
start to flatten out. This is because gravity is pulling downwards,
which means that the pressure is not equal in all directions and the
ball is deformed. The larger the oil ball, the more it will flatten.

Back to Krampf Index
Including permission to post these experiments on my web site.