Krampf - #174 Bad Chocolate?

Krampf@aol.com

Experiment - #174 Bad Chocolate?
It has to do with the white discoloration that you sometimes find on
old chocolate.

You will need:

a plastic food storage bag
chocolate - I used chocolate chips and bar chocolate, using milk
chocolate and semi-sweet chocolate.

Please read the safety warning before you start.
First, eat some of the chocolate. Notice the taste and the texture.
Since we are going to change the chocolate, we need a control to
compare the results with. Keep plenty of chocolate handy, as I found it
necessary to refresh my memory frequently. I ate almost an entire bag
of semi-sweet chocolate chips just to be sure I was familiar with their
flavour.

Next, we are going to cause the chocolate to "bloom". That is the term
that is used in the chocolate industry to describe the changes that
happen in old chocolate. To do this, put some chocolate into the
plastic bag. We want to heat the chocolate enough to partially melt it,
without turning it into a puddle. I placed the bag on the dashboard of
my truck and left it there for about 5 minutes. This worked much better
than using the microwave, which tended to melt them too quickly. The
chocolate should be soft, but should still be in a lump, not a runny
liquid. If the chocolate melts completely, then get some fresh
chocolate and try again.

Once you have some partially melted chocolate, place the bag someplace
where no one will eat it. By the following day, you should notice quite
a change. The surface of the chocolate probably is lighter colour and
has very light coloured blotches. Break off a piece and taste it. Don't
worry, the light splotches are not mold. While the taste has not
changed much, you will notice a big difference in the texture. Instead
of being smooth, the chocolate now feels grainy. Be sure to eat some
more fresh chocolate to compare the two.

What has happened? The light coloured patches are cocoa butter, one of
the main ingredients in chocolate. When cool enough to be solid, cocoa
butter forms crystals. It is polymorphic, which means that at different
temperatures, it forms different kinds of crystals. For chocolate to be
smooth and creamy, the crystals must be very small. When we melted the
chocolate and let it cool again, it formed larger crystals, giving it a
grainy texture.

Cocoa butter is monotropic, which means that even if it does not melt,
over time the small crystals will slowly change to the larger form. To
prevent this, chocolate should be kept in a cool, dry place, but not in
the freezer. If frozen, condensation can leach out the sugar, again
causing white blotches. I feel that by far the best strategy for
chocolate is to eat it all quickly, before it has a chance to go bad.

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